Lorentz Contact Resonance

The Lorentz Contact Resonance (LCR) imaging mode further enhances the capabilities of the afm+ and nanoIR systems. LCR allows rapid broadband nanomechanical measurements over a range of temperatures, identifying key sample measurement contrasts, and allowing precise probe placement for subsequent chemical or thermal analysis with nanoscale resolution.

How it works

Lorentz Contact Resonance is based on the Lorentz force, the force on an electrical current in a magnetic field. An oscillating current passing through the Thermalever™ probe interacts with a magnetic field that is focused near the probe, resulting in a perpendicular oscillating tip sample force. The frequency of the oscillating current on the cantilever can be rapidly changed to measure nanomechanical spectra of contact resonances.

LCR Multi-Component polymer blend



 

Driving the tip in this fashion, instead of with a piezoelectric crystal, has many advantages, including no moving parts in the drive system leading to clean cantilever resonance spectra with no parasitic peaks.

Because there are no moving parts actuating the cantilever, Lorentz Contact Resonance provides a very clean excitation over broad frequency ranges (bottom plot). Piezo drive schemes (top plot) can excite many spurious resonances that interfere with contact resonance measurements and interpretation of the results.

LCR Multi-Component polymer blend

Mechanical property insights

Our Analysis Studio software allows frequency sweeps over a wide range (1 kHz to 4 MHz). By placing the Thermalever™ probe on the sample surface and sweeping the entire frequency range, mechanical spectra of the surface can be obtained, showing differing stiffness properties via amplitudes or shifted peaks at the resonant frequencies of the cantilever.



Left: A selection of LCR nanomechanical spectra obtained on different polymers. Different polymers can be distinguished on the basis of position and/or height of contact resonances in the LCR spectra.

Applications

Polymer blend

Multi-component samples can be imaged at multiple frequencies, identifying and imaging each component individually. The Analysis Studio software can then be used to create an RGB overlay image.

PS-LDPE Blend


Wood

Three color mechanical map of wood cells. This composite image was made by overlying the LCR amplitudes collected at three different contact resonances. These resonances were selected to highlight the varying ratios of the lignin and cellulose which compose the sample.

PS-LDPE Blend


Nanomechanical Spectroscopy

AFM image (left) and a series of Lorentz Contact Resonance mechanical spectra (right) on a blend of polystyrene (PS) and low density polyethylene (LDPE). LCR spectra clearly distinguish the PS and LDPE by the positions and amplitudes of the resonant peaks.

Nanomechanical Spectroscopy


Compositional Mapping

LCR provides high resolution maps of material components in heterogeneous materials.

AFM image (left) and LCR composite image (right) of a polymer blend. This image was created by combining LCR amplitude images at three different contact resonances to highlight the distribution of the blend components. Lee et. al., Nanotechnology 2012, 23, 055709.

LCR Multi-Component polymer blend